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One of the reasons that I love IchiRuki is the fact that one person seems to "feel" what the other is thinking about. *cough* The scene where Rukia tells Ichigo to get his act together and she knows why he's not being his usual self. You could really see how surprised Ichigo was after Rukia told him that she knew about his hollow problem. After that moment, Rukia made Ichigo feel better about himself and he was more determined to become stronger.
I love how they have playful little fights with little things, like Ichigo mocking Rukia's drawings. I have a whole list of reasons why I adore the couple but I don't want to page stretch or anything. xD;