Haha, I'm a huuuge Bond fan (and I've seen every film), so I probably won't listen to the track 'till I watch the movie. But, some of my particular favorites:
Goldeneye
The Living Daylights
A View to a Kill
For Your Eyes Only
License to Kill
Goldfinger
The World is Not Enough
All Time High (Octopussy)
Some of the video game themes are pretty damn great too if you haven't heard those.
"Nearly Civilized" (Nightfire) - Esthero
"Everything or Nothing" - Mya
"I'll Take It All" (Blood Stone) - Joss Stone
I actually like them all on a level or another -- except the Jack White/Alicia Keys one, god, that was utterly crappy. That movie was the worst Bond I ever watched too.
Here's an alternate rejected "Quantum of Solace" title theme written/performed by some obscure artists, which might sound typical of a Bond track, but it's pretty damn great regardless:
http://www.youtube.com/watch?v=zg2dXY9TOKA